|
Kinetics of thermal
substitution reactions of some Chromium (III) -alkyl amine
complexes in mixed solvent media
A. Rajendran1* and K.
Anbalagan2
1Department
of Chemistry, Sir Theagaraya College, Chennai- 620 021,
Tamil Nadu, India.
2Department
of Inorganic Chemistry, Pondicherry University,
Puducherry-605 014, India.
*Corresponding author. E-mail:
annamalai_rajendran2000@yahoo.com.
Accepted
4 January, 2010 |
|
|
Molecular dynamics
of the aquation reactions of the complexes [Cr(en)2Cl2]Cl,
[Cr(tn)2Cl2]Cl, [Cr(tetren)Cl]Cl2,
[Cr(pn)2Cl2]Cl, [Cr(trien)Cl2]Cl and
[Cr(dien)Cl3] have been extensively studied in mixed solvent
media. Kinetics and thermodynamic parameters have been evaluated and the
results are interpreted carefully in the light of statistical and
regression models.
Key words:
Cr (III) complexes, molecular dynamics, aquation reaction, kinetic
parameters, thermodynamic parameter, statistical model, regression
model. |
