|
|
|
|
African Journal of Pure and Applied Chemistry Vol.
4 (1), pp. 001-006, January, 2010 ISSN 1996-0840
© 2010 Academic Journals |
|
Full Length
Research Paper
|
|
Utilization of amino
resin for emulsion paint formulation: Effect of urea
formaldehyde viscosity on urea formaldehyde and soybean oil
copolymer composite
S. A. Osemeahon*, I. I. Nkafamiya, C. Milam and U. U. Modibbo
Department of Chemistry, Federal University of Technology,
Yola, Adamawa State, Nigeria.
*Corresponding author. E-mail:
sundayosemeahon@yahoo.com.
Accepted
4 December, 2009. |
|
|
|
|
Abstract |
|
|
|
In our continuous
desire to develop a paint binder from amino resin, the effect of urea
formaldehyde (UF) viscosity on a copolymer composite derived from the
copolymerization reaction between urea formaldehyde (UF) and soybean oil
(SBO) to give urea formaldehyde/ soybean oil copolymer composite (UF/SBO)
was investigated. Some physical properties of (UF/SBO) obtained at
different viscosities (5.11 - 260.04 mPa.s) were evaluated. The melting
point, density and formaldehyde emission were found to increase with
increase in UF viscosity while the dry time, moisture uptake refractive
index and elongation at break were found to decrease with increase in UF
viscosity. UF viscosity below 150.00 mPa.s was found to produce UF/SBO
copolymer composite that is soluble in water. The processing of UF/SBO
copolymer resin for emulsion paint formulation should be carried out
below this viscosity level. The copolymer composite was found to be
ductile throughout the viscosity range studied (5.11 - 260.04). This
takes care of the inherent brittleness associated with the traditional
UF and will give paint formulators freedom of choice as regards
processing viscosity of UF/SBO. The results obtained from this
experiment will offer formulator different options and to control
formulation processes towards developing UF/SBO copolymer composite as a
paint binder for emulsion paint formulation.
Key words:
Copolymerization, viscosity, amino resin, paint binder. |
|
|